Postsynthetic Metalated MOFs as Atomically Dispersed Catalysts for Hydroformylation Reactions
Articolo
Data di Pubblicazione:
2020
Abstract:
A manganese-based metal-organic framework with dipyrazole ligands has been metalated with atomically dispersed Rh and Co species and used as a catalyst for the hydroformylation of styrene. The Rh-based materials exhibited excellent conversion at 80 °C with complete chemoselectivity, high selectivity for the branched aldehyde, high recyclability, and negligible metal leaching.
Tipologia CRIS:
01.01 - Articolo in rivista
Keywords:
heterogeneous catalysis; hydroformylation of olefins; metal-organic frameworks; rhodium coordination compounds; single-atom catalysts
Elenco autori:
Tang, P.; Paganelli, S.; Carraro, F.; Blanco, M.; Ricco, R.; Marega, C.; Badocco, D.; Pastore, P.; Doonan, C. J.; Agnoli, S.
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